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SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU

Year 2012, Volume: 27 Issue: 2, 31 - 37, 01.06.2012

Sezen Küçükçongar Mehmet Faik Sevimli Esra Yel

Abstract

Doğal organik maddeler (DOM) tüm yüzeysel sularda ve yeraltı sularında kompleks reaksiyonların bir sonucu olarak bulunduğundan oldukça heterojen bir bileşimdedir. DOM’in yaklaşık %90’ı sularda çözünmüş formda bulunmaktadır ve bu çözünmüş organik maddeler (ÇOM) içerisinde sucul hümik maddeler (SHM) en yüksek miktarda bulunan fraksiyondur. Su kaynaklarına yönelik çalışmalarda SHM’lere ilginin artmasındaki temel nedenlerden birincisi, içme suyu arıtımında kullanılan farklı oksidan ve dezenfektanlarla verdikleri reaksiyonlar sonucu insan sağlığı için zararlı olan dezenfeksiyon yan ürünlerini (trihalometanlar, haloasetik asitler vd.) oluşturmasıdır. İkinci neden ise su ortamlarında organik ve inorganik pek çok kirletici ile kompleks oluşturması veya sorplayarak suda taşımaya eğilimli olmasıdır. SHM’lerin sulardan izolasyonunda çok farklı yöntemler uygulanabilmektedir. Farklı reçineler kullanarak uygulanan reçine adsorpsiyon kromatografi (RAK) tekniği, yüksek hacimlerdeki sulardan SHM’leri gidermek ve konsantre hale getirmek için sıklıkla kullanılan bir metottur. Bu çalışmada RAK yönteminde Amberlite XAD-8, Bio-Rad AG-MP-50 ve Duolite A-7 reçineleri kullanılarak ÇOM fraksiyonlarına ayırma yöntemi uygulanmıştır. Reçineler, literatürde geliştirilen metotlar ve bazı modifikasyonlarla temizleme ve şartlandırma işlemlerine tabi tutulmuştur. Farklı yüzeysel su kaynaklarından alınan numunelere RAK yöntemi uygulanarak hidrofobik ve hidrofilik özelliklerine göre altı farklı fraksiyon elde edilmiştir. Bu fraksiyonların farklı yüzeysel su kaynakları için yüzde dağılımları belirlenmiştir.

Keywords

Doğal organik madde fraksiyonlama reçine adsorpsiyon kromatografi

References

  • Andersen, D.O., Alberts, J.J., Takacs, M., 2000, “Nature of Natural Organic Matter (NOM) in Acidified and Limed Surface Waters”, Water Res., Vol. 34, No. 1, pp. 266-278.
  • APHA/AWWA/WEF, 2005, Standard Methods for the Examination of Water and Wastewater, 21th Ed.; American Public Health Association, Washington D.C., USA.
  • Bezbarua, B. K., 1997, Modeling Reactions of Ozone with Natural Organic Matter, Ph.D. Thesis, University of Massachussets Amherst.
  • Chen, K.-C., 2003, Ozonation, Ultrafiltration and Biofiltration for the Control of NOM and DBP in Drinking Water, Ph.D. Thesis, Michigan State University.
  • Cho, J., Amy, G., Pellegrino, J., 2000, “Membrane Filtration of Natural Organic Matter: Factors and Mechanisms Affecting Rejection and Flux Decline With Charged Ultrafiltration (UF) Membrane”, Membrane Sci., Vol. 164, pp. 89-110.
  • Croue, J.P., Martin, B., Simon, P. and Legube, B., 1993, “Les matieres hydrophobes et hydrophiles des eaux de retenue- extraction, caracterisation et quantification”, Water Supply,Vol. 11, pp. 79-90.
  • Crum, R.H., Murphy, E.M., Keller, C.K., 1996, “A Non-Adsorptive Method for the Isolation and Fractionation of Natural Dissolved Organic Carbon”, Water Res., Vol. 30, No. 5, pp. 1304-1311.
  • Day, G.M., Beckett, R., Hart, B. and McKelvie, I., 1991, “Characterization of natural organic matter from four Victorian freshwater systems”, Aust J Mar Freshwater Res, Vol. 42, pp. 675-687.
  • Kilduff, J.E., Mattaraj, S., Wigton, A., Kitis, M., Karanfil, T., 2004, “Effects of Reverse Osmosis Isolation on Reactivity of Naturally Occuring Dissolved Organic Matter in Physicochemical Processes”, Water Res., Vol. 38, pp. 1026-1036.
  • Kim, H.-C., Yu, M.J., Han, I., 2006, “Multi-Method Study of Characteristic Chemical Nature of Aquatic Humic Substances Isoalted From the Han River, Korea”, Applied Geochemistry, Vol. 21, pp. 1226-1239.
  • Kitiş, M., 2001, Probing Chlorine Reactivity of Dissolved Organic Matter for Disinfection By-Product (DBP) Formation: Relations with Specific Ultraviolet Absorbance (SUVA) and Development of the DBP Reactivity Profile, Ph.D. Thesis, Clemson University.
  • Leenheer, J.A., 1981, “Comprehensive Approach to Preparative Isolation and Fractionation of Dissolved Organic Carbon from Natural Waters and Wastewaters”, Environmental Science & Technology, Vol. 15, No. 5, pp. 578-587.
  • Ma, H., Allen, H.E., Yin, Y., 2001, “Characterization of Isolated Fractions of Dissolved Organic Matter From Natural Waters and a Wastewater Effluent”, Water Res., Vol. 35, No. 4, pp. 985-996.
  • Marhaba, T.F., Van, D., 2000, “The Variation of Mass and Disinfection By-Product Formation Potential of Dissolved Organic Matter Fractions Along A Conventional Surface Water Treatment Plant”, J. Hazard. Mater., Vol. A74, pp. 133-147.
  • Peuravuori, J., Pihlaja, K., 1997, “Isolation and Characterization of Natural Organic Matter From Lake Water: Comparison of Isolation With Solid Adsorption and Tangential Membrane Filtration”, Environ. Int., Vol. 23, No. 4, pp. 441-451.
  • Schafer, A.I., 2001, Natural Organics Removal Using Membranes, Principles, Performance and Cost, Technomic Publishing, Pp: 365.
  • Serkiz, S.M., Perdue, E.M., 1990, “Isolation of Dissolved Organic Matter from the Suwannee River Using Reverse Osmosis”, Water Res., Vol. 24, pp. 911-916.
  • Swietlik, J., Dabrowska, A., Raczyk-Stanislawiak, U., Nawrocki, J., 2004, “Reactivity of Natural Organic Matter Fractions with Chlorine Dioxide and Ozone”, Water Res., Vol. 38, pp. 547-558.
  • Thurman, E.M., Malcolm, R.L., 1981, “Preparative Isolation of Aquatic Humic Substances”, Environmental Science & Technology, Vol. 15, No. 4, pp. 463-466.

Isolation of Aquatic Humic Matter by Resin Adsorption Chromatography Technique

Year 2012, Volume: 27 Issue: 2, 31 - 37, 01.06.2012

Sezen Küçükçongar Mehmet Faik Sevimli Esra Yel

Abstract

Natural organic matter (NOM) in surface waters and ground waters are heterogeneous compositions as a result of complex reactions. Approximately 90% of NOM is dissolved form in waters and aquatic humic matter (AHM) is the highest fraction of dissolved organic matter (DOM). The first of the main reasons for increased interest of AHM’s in water resources studies is the formation of disinfection by-products (trihalomethanes, halo acetic acids etc.) that are harmful for human health reacting with different oxidant and disinfectant used in drinking water treatment. The second reason is formation complex with organic and inorganic pollutants or sorption for transportation in water. There are many different methods for isolation of AHM’s from waters. Resin adsorption chromatography (RAC) technique used different resins, is a method widely used for the removal of AHMs from waters and to concentrate of AHMs. In this study, RAC method with using Amberlite XAD-8, Bio-Rad AG-MP-50 and Duolite A-7 resins was applied for fractionation of DOM in water. Resins were cleaned and conditioned with according to methods and modifications in the literature. RAC method was applied to different surface water samples and six different fractions were obtained according to the hydrophobic and hydrophilic properties for each water sample. Percentage distributions of these fractions of these fractions were determined for different surface water sources.

Keywords

Natural organic matter fractionation resin adsorption chromatography

References

  • Andersen, D.O., Alberts, J.J., Takacs, M., 2000, “Nature of Natural Organic Matter (NOM) in Acidified and Limed Surface Waters”, Water Res., Vol. 34, No. 1, pp. 266-278.
  • APHA/AWWA/WEF, 2005, Standard Methods for the Examination of Water and Wastewater, 21th Ed.; American Public Health Association, Washington D.C., USA.
  • Bezbarua, B. K., 1997, Modeling Reactions of Ozone with Natural Organic Matter, Ph.D. Thesis, University of Massachussets Amherst.
  • Chen, K.-C., 2003, Ozonation, Ultrafiltration and Biofiltration for the Control of NOM and DBP in Drinking Water, Ph.D. Thesis, Michigan State University.
  • Cho, J., Amy, G., Pellegrino, J., 2000, “Membrane Filtration of Natural Organic Matter: Factors and Mechanisms Affecting Rejection and Flux Decline With Charged Ultrafiltration (UF) Membrane”, Membrane Sci., Vol. 164, pp. 89-110.
  • Croue, J.P., Martin, B., Simon, P. and Legube, B., 1993, “Les matieres hydrophobes et hydrophiles des eaux de retenue- extraction, caracterisation et quantification”, Water Supply,Vol. 11, pp. 79-90.
  • Crum, R.H., Murphy, E.M., Keller, C.K., 1996, “A Non-Adsorptive Method for the Isolation and Fractionation of Natural Dissolved Organic Carbon”, Water Res., Vol. 30, No. 5, pp. 1304-1311.
  • Day, G.M., Beckett, R., Hart, B. and McKelvie, I., 1991, “Characterization of natural organic matter from four Victorian freshwater systems”, Aust J Mar Freshwater Res, Vol. 42, pp. 675-687.
  • Kilduff, J.E., Mattaraj, S., Wigton, A., Kitis, M., Karanfil, T., 2004, “Effects of Reverse Osmosis Isolation on Reactivity of Naturally Occuring Dissolved Organic Matter in Physicochemical Processes”, Water Res., Vol. 38, pp. 1026-1036.
  • Kim, H.-C., Yu, M.J., Han, I., 2006, “Multi-Method Study of Characteristic Chemical Nature of Aquatic Humic Substances Isoalted From the Han River, Korea”, Applied Geochemistry, Vol. 21, pp. 1226-1239.
  • Kitiş, M., 2001, Probing Chlorine Reactivity of Dissolved Organic Matter for Disinfection By-Product (DBP) Formation: Relations with Specific Ultraviolet Absorbance (SUVA) and Development of the DBP Reactivity Profile, Ph.D. Thesis, Clemson University.
  • Leenheer, J.A., 1981, “Comprehensive Approach to Preparative Isolation and Fractionation of Dissolved Organic Carbon from Natural Waters and Wastewaters”, Environmental Science & Technology, Vol. 15, No. 5, pp. 578-587.
  • Ma, H., Allen, H.E., Yin, Y., 2001, “Characterization of Isolated Fractions of Dissolved Organic Matter From Natural Waters and a Wastewater Effluent”, Water Res., Vol. 35, No. 4, pp. 985-996.
  • Marhaba, T.F., Van, D., 2000, “The Variation of Mass and Disinfection By-Product Formation Potential of Dissolved Organic Matter Fractions Along A Conventional Surface Water Treatment Plant”, J. Hazard. Mater., Vol. A74, pp. 133-147.
  • Peuravuori, J., Pihlaja, K., 1997, “Isolation and Characterization of Natural Organic Matter From Lake Water: Comparison of Isolation With Solid Adsorption and Tangential Membrane Filtration”, Environ. Int., Vol. 23, No. 4, pp. 441-451.
  • Schafer, A.I., 2001, Natural Organics Removal Using Membranes, Principles, Performance and Cost, Technomic Publishing, Pp: 365.
  • Serkiz, S.M., Perdue, E.M., 1990, “Isolation of Dissolved Organic Matter from the Suwannee River Using Reverse Osmosis”, Water Res., Vol. 24, pp. 911-916.
  • Swietlik, J., Dabrowska, A., Raczyk-Stanislawiak, U., Nawrocki, J., 2004, “Reactivity of Natural Organic Matter Fractions with Chlorine Dioxide and Ozone”, Water Res., Vol. 38, pp. 547-558.
  • Thurman, E.M., Malcolm, R.L., 1981, “Preparative Isolation of Aquatic Humic Substances”, Environmental Science & Technology, Vol. 15, No. 4, pp. 463-466.
There are 19 citations in total.

Details

Other ID JA47EG35JJ
Journal Section Articles
Authors

Sezen Küçükçongar

Mehmet Faik Sevimli This is me

Esra Yel This is me

Publication Date June 1, 2012
Published in Issue Year 2012 Volume: 27 Issue: 2

Cite

APA Küçükçongar, S., Sevimli, M. F., & Yel, E. (2012). SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 27(2), 31-37.
AMA Küçükçongar S, Sevimli MF, Yel E. SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU. sujest. June 2012;27(2):31-37.
Chicago Küçükçongar, Sezen, Mehmet Faik Sevimli, and Esra Yel. “SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 27, no. 2 (June 2012): 31-37.
EndNote Küçükçongar S, Sevimli MF, Yel E (June 1, 2012) SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 27 2 31–37.
IEEE S. Küçükçongar, M. F. Sevimli, and E. Yel, “SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU”, sujest, vol. 27, no. 2, pp. 31–37, 2012.
ISNAD Küçükçongar, Sezen et al. “SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 27/2 (June 2012), 31-37.
JAMA Küçükçongar S, Sevimli MF, Yel E. SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU. sujest. 2012;27:31–37.
MLA Küçükçongar, Sezen et al. “SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, vol. 27, no. 2, 2012, pp. 31-37.
Vancouver Küçükçongar S, Sevimli MF, Yel E. SU KAYNAKLARINDA HÜMİK MADDELERİN REÇİNE ADSORPSİYON KROMATOGRAFİ TEKNİĞİ İLE İZOLASYONU. sujest. 2012;27(2):31-7.

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